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Diels−Alder Chemistry of Graphite and Graphene: Graphene as Diene and Dienophile

2011; American Chemical Society; Volume: 133; Issue: 10 Linguagem: Inglês

10.1021/ja200118b

1943-2984

Santanu Sarkar, Elena Bekyarova, Sandip Niyogi, Robert C. Haddon,

Fullerene Chemistry and Applications

The zero-band-gap electronic structure of graphene enables it to function as either the diene or the dienophile in the Diels-Alder reaction, and this versatile synthetic method offers a powerful strategy for the reversible modification of the electronic properties of graphene under very mild conditions.