Porous Zirconium Metal–Organic Framework Constructed from 2D → 3D Interpenetration Based on a 3,6-Connected kgd Net
2014; American Chemical Society; Volume: 53; Issue: 14 Linguagem: Inglês
10.1021/ic5012764
ISSN1520-510X
AutoresRongming Wang, Zhiying Wang, Yuwen Xu, Fangna Dai, Liangliang Zhang, Daofeng Sun,
Tópico(s)Radioactive element chemistry and processing
ResumoA new porous zirconium metal–organic framework (Zr MOF), Zr6(μ3-O)4(μ3-OH)4(OH)6(H2O)6(BTB)2·6DMF·H2O (1; H3BTB = 5′-(4-carboxyphenyl)[1,1′:3′,1″-terphenyl]-4,4″-dicarboxylic acid), based on Zr6 clusters and tricarboxylate ligands has been constructed and characterized. The Zr6 clusters were linked by BTB ligands to generate a 2D network of kgd topology. The interpenetrations among the 2D networks gave rise to a 3D porous framework, which represents the first Zr MOF constructed from 2D → 3D interpenetration. The gas uptake and catalytic properties for 1 have also been studied.
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