Superabsorbent Hydrogels That Are Robust and Highly Stretchable
2014; American Chemical Society; Volume: 47; Issue: 13 Linguagem: Inglês
10.1021/ma500882n
ISSN1520-5835
AutoresBani H. Cipriano, Stephen J. Banik, Renu Sharma, Dominic Rumore, Wonseok Hwang, Robert M. Briber, Srinivasa R. Raghavan,
Tópico(s)Advanced Materials and Mechanics
ResumoPolymer hydrogels synthesized by chemical cross-linking of acrylate or acrylamide monomers can absorb more than 100 times their weight in water. However, such gels are usually fragile and rupture when stretched to moderate strains (∼50%). Many strategies have been developed to create tougher gels, including double-networking, incorporation of nanoparticles as cross-linkers, etc., but these strategies typically retard the water absorbency of the gel. Here, we present a new approach that gives rise to superabsorbent hydrogels having superior mechanical properties. The key to our approach is the self-cross-linking ability of N,N-dimethylacrylamide (DMAA). That is, we conduct a free-radical polymerization of DMAA (along with an ionic comonomer such as sodium acrylate) but without any multifunctional monomers. A hydrogel still forms due to interchain covalent bonds between the growing linear polymer chains. Gels formed by this route can be stretched up to 1350% strain in the unswollen state. The same gels are also superabsorbent and can imbibe up to 3000 times their weight in water (which is believed to be a record). Even in the swollen state, these gels can be stretched up to strains ∼400% before rupture, which substantially exceeds that of conventional superabsorbent gels. The superior properties of DMAA-based gels are attributed to a more uniform distribution of cross-links within their networks.
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