Platinum‐Catalyzed Synthesis of β‐Keto Tetrahydropyrans and Cyclic Dienolethers
2011; Wiley; Volume: 6; Issue: 8 Linguagem: Inglês
10.1002/asia.201100113
ISSN1861-4728
AutoresQiren Liang, Mingxing Qian, Mina Razzak, Jef K. De Brabander,
Tópico(s)Asymmetric Synthesis and Catalysis
ResumoChemistry – An Asian JournalVolume 6, Issue 8 p. 1958-1960 Communication Platinum-Catalyzed Synthesis of β-Keto Tetrahydropyrans and Cyclic Dienolethers Dr. Qiren Liang, Dr. Qiren Liang Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Search for more papers by this authorDr. Mingxing Qian, Dr. Mingxing Qian Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Search for more papers by this authorDr. Mina Razzak, Dr. Mina Razzak Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Search for more papers by this authorProf. Jef K. De Brabander, Corresponding Author Prof. Jef K. De Brabander jef.debrabander@utsouthwestern.edu Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Search for more papers by this author Dr. Qiren Liang, Dr. Qiren Liang Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Search for more papers by this authorDr. Mingxing Qian, Dr. Mingxing Qian Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Search for more papers by this authorDr. Mina Razzak, Dr. Mina Razzak Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Search for more papers by this authorProf. Jef K. De Brabander, Corresponding Author Prof. Jef K. De Brabander jef.debrabander@utsouthwestern.edu Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Department of Biochemistry and Simmons Comprehensive Cancer Center, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038 (USA), Fax: (+1) 214-648-0320Search for more papers by this author First published: 04 May 2011 https://doi.org/10.1002/asia.201100113Citations: 6Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract A platinum upgrade: Zeise's dimer [{Cl2Pt(CH2CH2)}2] catalyzes the activation of linear propargylic alcohols and esters. Depending on the presence of a suitably placed alcohol group proximal or distal to the propargylic center, a cyclo-reorganization occurs that delivers either valuable β-keto tetrahydropyrans (from propargylic alcohols), or cyclic dienolethers (from propargylic esters). Citing Literature Volume6, Issue8Special Issue: Eun Lee's Retirement and 65th BirthdayAugust 1, 2011Pages 1958-1960 RelatedInformation
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