Ligand-Free Ni-Catalyzed Reductive Cleavage of Inert Carbon–Sulfur Bonds
2012; American Chemical Society; Volume: 14; Issue: 3 Linguagem: Inglês
10.1021/ol2033306
ISSN1523-7060
AutoresNekane Barbero, Rubén Martı́n,
Tópico(s)Catalytic Cross-Coupling Reactions
ResumoA catalytic reductive cleavage of C(sp2)– and C(sp3)–SMe bonds under ligandless conditions is presented. The method is characterized by its wide scope and high chemoselectivity profile including challenging substrate combinations, allowing the design of orthogonal and site-selectivity approaches.
Referência(s)