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Chirality in Diarylether Heptanoids: Synthesis of Myricatomentogenin, Jugcathanin, and Congeners

2012; American Chemical Society; Volume: 14; Issue: 15 Linguagem: Inglês

10.1021/ol301893t

1523-7060

M. Quamar Salih, Christopher M. Beaudry,

Plant Parasitism and Resistance

The syntheses of myricatomentogenin, jugcathanin, galeon, pterocarine, and acerogenin L are reported. Synthetic material was used to measure their optical activities and free energy of activation for racemization. The natural enantiomers of myricatomentogenin, jugcathanin, galeon, and pterocarine were determined to have the same pR absolute stereochemistry. Acerogenins L and C are achiral compounds.