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Characterization and Bonding of the Cation [Ge{N(C 6 H 3 -2,6- i -Pr 2 )CMe} 2 CH] + : Comparison with the Isoelectronic Ga{N(C 6 H 3 -2,6- i -Pr 2 )CMe} 2 CH

2001; American Chemical Society; Volume: 40; Issue: 21 Linguagem: Inglês

10.1021/ic0155582

1520-510X

Matthias Stender, A.D. Phillips, Philip P. Power,

Organoboron and organosilicon chemistry

Reaction of Ge(Cl)Dipp2nacnac (Dipp2nacnac = {N(C6H3-2,6-i-Pr2)C(Me)}2CH) with B(C6F5)3 in the presence of H2O affords the salt [Ge(Dipp2nacnac)][HO{B(C6F5)3}2] whose cation [Ge(Dipp2nacnac)]+ is isoelectronic to its neutral gallium analogue Ga(Dipp2nacnac).