Al 16 P 20 O 80 H 4 ·4C 6 H 18 N 2 : A New Microporous Aluminophosphate Containing Intersecting 12- and 8-Membered Ring Channels
1998; American Chemical Society; Volume: 10; Issue: 5 Linguagem: Inglês
10.1021/cm980019p
ISSN1520-5002
AutoresJihong Yu, K. Sugiyama, Shou‐Tian Zheng, Shilun Qiu, J. Chen, Ruren Xu, Yasuhiro Sakamoto, Osamu Terasaki, K. Hiraga, Mark E. Light, Michael B. Hursthouse, J. M. Thomas,
Tópico(s)Zeolite Catalysis and Synthesis
ResumoA new microporous aluminophosphate, designated AlPO-HDA, is prepared under solvothermal conditions using 1,6-hexanediamine as the template. AlPO-HDA is the first microporous aluminophosphate with Al/P ratio of 4/5. The structure is characterized by a series of double six-rings sharing 4-MR with each other stacked along the b direction. These columns of double six-rings interconnect through 4-MR to form layers that are further connected together through PO2(O)(OH) tetrahedra to build up the three-dimensional framework with intersecting 12-MR and 8-MR channels.
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