Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands
2010; American Chemical Society; Volume: 132; Issue: 43 Linguagem: Inglês
10.1021/ja107115q
ISSN1943-2984
AutoresVlad M. Iluc, Gregory L. Hillhouse,
Tópico(s)Synthesis and characterization of novel inorganic/organometallic compounds
ResumoHydrogen-atom abstraction from M−E(H) to generate M═E-containing complexes (E = PR, NR) is not well studied because only a few complexes are known to undergo such reactions. Hydrogen-atom abstraction from nickel(I) phosphide and amide complexes led to the corresponding phosphinidene and imide compounds. These reactions are unparalleled in the organometallic chemistry of nickel and feature an unusual example of a transition-metal phosphinidene synthesized by hydrogen-atom abstraction.
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