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BIBTEX RIS

Understanding the Effect of Adsorption Geometry over Substrate Selectivity in the Surface-Enhanced Raman Scattering Spectra of Simazine and Atrazine

2011; American Chemical Society; Volume: 115; Issue: 10 Linguagem: Inglês

10.1021/jp112021j

ISSN

1932-7455

Autores

J. Costa, Rômulo A. Ando, Pedro H. C. Camargo, Paola Cório,

Tópico(s)

Melamine detection and toxicity

Resumo

This paper studies the selectivity of well-defined Au and Ag nanostructures as substrates for the SERS (surface-enhanced Raman scattering) detection of simazine (6-chloro-N,N′-diethyl-1,3,5-triazine-2,4-diamine) and atrazine (6-chloro-N-ethyl-N′-isopropyl-1,3,5-triazine-2,4-diamine). Our data showed that simazine and atrazine displayed similar SERS spectra when the Au was employed as substrate. Conversely, distinct SERS signatures were obtained upon the utilization of Ag substrates. Density functional theory (DFT) calculations and vibrational assignments suggested that, while simazine and atrazine adsorbed on Au via the N3 position of the triazine ring, simazine adsorbed on Ag via N3 and atrazine via N5. The results presented herein demonstrated that the adsorption geometry of analyte molecules can play a central role over substrate selectivity in SERS, which is particularly important in applications involving ultrasensitive analysis of mixtures containing structurally similar molecules.

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