Unexpected Michael Additions on the Way to 2.3,8.9‐Dibenzanthanthrenes with Interesting Structural Properties
2016; Wiley; Volume: 22; Issue: 27 Linguagem: Inglês
10.1002/chem.201601435
ISSN1521-3765
AutoresChristian Reus, Marc P. Lechner, Matthias B. Schulze, Dominik Lungerich, Colin Diner, Marco Gruber, Jeffrey M. Stryker, Frank Hampel, Norbert Jux, Rik R. Tykwinski,
Tópico(s)Porphyrin and Phthalocyanine Chemistry
ResumoThe synthesis and properties of a new polycyclic aromatic hydrocarbon containing eight annulated rings and based on the anthanthrene core is described. An unexpected, nucleophile-dependent Michael addition to a dibenzanthanthrene-1,7-dione is found, giving a product with three triisopropylsilylacetylene units and a remarkable solid-state structure (as determined by X-ray crystallography).
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