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A flexible and robust neural network IASI‐NH 3 retrieval algorithm

2016; Wiley; Volume: 121; Issue: 11 Linguagem: Inglês

10.1002/2016jd024828

2169-8996

Simon Whitburn, Martin Van Damme, Lieven Clarisse, Sophie Bauduin, Colette L. Heald, J. Hadji‐Lazaro, D. Hurtmans, Mark A. Zondlo, Cathy Clerbaux, P.-F. Coheur,

Atmospheric chemistry and aerosols

Abstract In this paper, we describe a new flexible and robust NH 3 retrieval algorithm from measurements of the Infrared Atmospheric Sounding Interferometer (IASI). The method is based on the calculation of a spectral hyperspectral range index (HRI) and subsequent conversion to NH 3 columns via a neural network. It is an extension of the method presented in Van Damme et al. (2014a) who used lookup tables (LUT) for the radiance‐concentration conversion. The new method inherits the advantages of the LUT‐based method while providing several significant improvements. These include the following: (1) Complete temperature and humidity vertical profiles can be accounted for. (2) Third‐party NH 3 vertical profile information can be used. (3) Reported positive biases of LUT retrieval are reduced, and finally (4) a full measurement uncertainty characterization is provided. A running theme in this study, related to item (2), is the importance of the assumed vertical NH 3 profile. We demonstrate the advantages of allowing variable profile shapes in the retrieval. As an example, we analyze how the retrievals change when all NH 3 is assumed to be confined to the boundary layer. We analyze different averaging procedures in use for NH 3 in the literature, introduced to cope with the variable measurement sensitivity and derive global averaged distributions for the year 2013. A comparison with a GEOS‐Chem modeled global distribution is also presented, showing a general good correspondence (within ±3 × 10 15 molecules.cm −2 ) over most of the Northern Hemisphere. However, IASI finds mean columns about 1–1.5 × 10 16 molecules.cm −2 (∼50–60%) lower than GEOS‐Chem for India and the North China plain.