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Highly Water-Stable Zirconium Metal–Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination

2015; American Chemical Society; Volume: 137; Issue: 22 Linguagem: Inglês

10.1021/jacs.5b02276

1943-2984

Xinlei Liu, Nilay Demir, Zhentao Wu, Kang Li,

Membrane-based Ion Separation Techniques

In this study, continuous zirconium(IV)-based metal-organic framework (Zr-MOF) membranes were prepared. The pure-phase Zr-MOF (i.e., UiO-66) polycrystalline membranes were fabricated on alumina hollow fibers using an in situ solvothermal synthesis method. Single-gas permeation and ion rejection tests were carried out to confirm membrane integrity and functionality. The membrane exhibited excellent multivalent ion rejection (e.g., 86.3% for Ca(2+), 98.0% for Mg(2+), and 99.3% for Al(3+)) on the basis of size exclusion with moderate permeance (0.14 L m(-2) h(-1) bar(-1)) and good permeability (0.28 L m(-2) h(-1) bar(-1) μm). Benefiting from the exceptional chemical stability of the UiO-66 material, no degradation of membrane performance was observed for various tests up to 170 h toward a wide range of saline solutions. The high separation performance combined with its outstanding water stability suggests the developed UiO-66 membrane as a promising candidate for water desalination.