Voltar
Artigo Acesso aberto Revisado por pares
BIBTEX RIS

Separation and Photophysical Properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ Stereoisomers of a Dinuclear Ruthenium(II) Complex

2001; American Chemical Society; Volume: 40; Issue: 21 Linguagem: Inglês

10.1021/ic010473m

ISSN

1520-510X

Autores

Wesley R. Browne, Christine O’Connor, Claudio Villani, Johannes G. Vos,

Tópico(s)

Magnetism in coordination complexes

Resumo

The separation of the four stereoisomers of [(Ru(bpy)2)2(bpt)](PF6)3 (where bpy = 2,2'-bipyridine, Hbpt = 3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semipreparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.

Referência(s)