Photomediated controlled radical polymerization
2016; Elsevier BV; Volume: 62; Linguagem: Inglês
10.1016/j.progpolymsci.2016.06.005
ISSN1873-1619
AutoresXiangcheng Pan, Mehmet Atilla Taşdelen, Joachim Laun, Tanja Junkers, Yusuf Yağcı, Krzysztof Matyjaszewski,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoPhotomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed.
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