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9 meso -Tetraarylporphyrin Derivatives: New Synthetic Methodologies

2010; World Scientific; Linguagem: Inglês

10.1142/9789814280228_0009

1793-9518

José A. S. Cavaleiro, Augusto C. Tomé, Maria G. P. M. S. Neves,

Cyclopropane Reaction Mechanisms

Handbook of Porphyrin ScienceHandbook of Porphyrin Science, pp. 193-294 (2010) No Access9 meso-Tetraarylporphyrin Derivatives: New Synthetic MethodologiesJosé A. S. Cavaleiro, Augusto C. Tomé, and Maria G. P. M. S. NevesJosé A. S. CavaleiroDepartment of Chemistry, QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal, Augusto C. ToméDepartment of Chemistry, QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal, and Maria G. P. M. S. NevesDepartment of Chemistry, QOPNA, University of Aveiro, 3810-193 Aveiro, Portugalhttps://doi.org/10.1142/9789814280228_0009Cited by:17 PreviousNext AboutSectionsPDF/EPUB ToolsAdd to favoritesDownload CitationsTrack CitationsRecommend to Library ShareShare onFacebookTwitterLinked InRedditEmail Abstract: The following sections are included: I. Introduction II. Porphyrins and Microwave-Assisted Synthesis A. Microwave-Assisted Synthesis of meso-Arylporphyrins and Metalloporphyrins B. Synthesis of New Porphyrin Derivatives by Microwave-Assisted Derivatization III. β-Functionalization of meso-Tetraarylporphyrins Mediated by Transition Metal Complexes A. Recent Bromination Procedures B. Porphyrin Functionalization through Stille and Suzuki Procedures C. The Sonogashira Approach to New Porphyrin Derivatives D. The Heck Reaction to New β-Substituted meso-Tetraarylporphyrins E. Synthesis of β-Alkenyl-Substituted Porphyrins via Metathesis Procedures F. Palladium-Catalyzed Carbon-Heteroatom Bond Formation in β-Substituted meso-Tetraarylporphyrins IV. Functionalization of Porphyrins through Cycloaddition Reactions A. Porphyrins as Dienophiles B. Porphyrins as Dienes C. Porphyrins as Dipolarophiles D. Porphyrins as 1,3-Dipoles E. Porphyrins in Click Chemistry V. Acknowledgments VI. 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