Artigo Acesso aberto Produção Nacional Revisado por pares

Modificação de membrana de poliamida via sol-gel e incorporação de composto de európio (III) luminescente

2016; Brazilian Chemical Society; Linguagem: Inglês

10.21577/0100-4042.20160122

ISSN

1678-7064

Autores

Érica Souza, Beatriz de Campos, Lucas A. Rocha, Emerson H. de Faria, Kátia J. Ciuffi, Jorge Vicente Lopes da Silva, Marcelo Oliveira, Izaque A. Maia,

Tópico(s)

biodegradable polymer synthesis and properties

Resumo

LUMINESCENT EUROPIUM (III) COMPLEX.Over the last decades, the combination of different technologies to search for systems with new properties and features has brought various segments of biological and earth sciences together.Additive manufacturing, known as rapid prototyping, combined with the sol-gel methodology enables the production of novel systems with applications in many scientific fields.In this work, flexible polyamide membranes were obtained by additive manufacturing, functionalized by the sol-gel methodology, and incorporated with the coordination compound between Eu(III) and 1,10-phenanthroline.The presence of vibrations at 1100 cm -1 in the FTIR spectrum of the material, which is a band typical of the Si-O-Si group in the alkoxide employed during the process, confirmed the polyamide membrane functionalization.The thermogravimetric curve showed that a residue remained after heating at 700 o C, which was attributed to SiO 2 .The membrane was highly luminescent, which confirmed incorporation of the Eu 3+ compound into the material and pointed to the possible application of this system as a topical medication for the treatment of skin diseases.

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