51 Photochemistry of Chlorophylls and Their Synthetic Analogs
2011; World Scientific; Linguagem: Inglês
10.1142/9789814322386_0003
ISSN1793-9518
AutoresHitoshi Tamiaki, Michio Kunieda,
Tópico(s)Marine and coastal ecosystems
ResumoHandbook of Porphyrin ScienceHandbook of Porphyrin Science, pp. 223-290 (2011) No Access51 Photochemistry of Chlorophylls and Their Synthetic AnalogsHitoshi Tamiaki and Michio KuniedaHitoshi TamiakiDepartment of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Kusatsu, Shiga 525-8577, Japan and Michio KuniedaDepartment of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Kusatsu, Shiga 525-8577, Japanhttps://doi.org/10.1142/9789814322386_0003Cited by:81 (Source: Crossref) PreviousNext AboutSectionsPDF/EPUB ToolsAdd to favoritesDownload CitationsTrack CitationsRecommend to Library ShareShare onFacebookTwitterLinked InRedditEmail Abstract: The following sections are included: List of Abbreviations I. Introduction II. Characterization of Chlorophylls A. Structures and Nomenclature B. Light Absorption III. Natural Chlorophylls A. In Photosynthetic Antennas B. In Organic Solvents 1. π-Skeletal Effect 2. Peripheral Substituent Effect a. 3-Substituents b. 7-Substituents c. 8-Substituents d. 12-Substituents e. 132-Substituents f. 17-Substituents g. 20-Substituents h. Central metals 3. Solvent Effects IV. Semisynthetic Chlorophylls A. π-Skeletons B. 3-Substituents 1. 3-Ethenyl Substituents (3-C=C) 2. 3-Ethynyl Substituents (3-C≡C) 3. 3-Carbonyl and Related Substituents (3-C=X) 4. 3-Monosubstituted-Methyl Substituents (3-CH2X) 5. 3-1-Monosubstituted-Alkyl Substituents (3-CHRX) 6. Carbinols (3-C(OH)RR′) 7. 3-Substituted Bacteriochlorins and Porphyrins C. 7,8-Substituents 1. 7-Substituents 2. 2. 8-Substituents 3. Formylated Chlorins 4. 3-Acetyl-Bacteriochlorins D. 13,15-Substituents 1. 13-Substituents 2. Modified 5-Membered E-Rings 3. Modified 6-Membered E-Rings 4. E-Ring-Opening Substituents E. 20-Substituents F. Central Metals G. π-Systems 1. B-Ring Reduced Chlorins 2. Stereoselectively D-Ring Reduced Chlorins 3. Isobacteriochlorins V. Fully-Synthetic Chlorophyll Models VI. Conclusions VII. Acknowledgments VIII. 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