Portal de Periódicos da CAPES

RECENT DEVELOPMENTS IN ASYMMETRIC CATALYSIS

2014; Linguagem: Inglês

10.1142/9781848168534_0012

2399-4495

Patrick Y. Toullec, Alexandre Pradal, Véronique Michelet,

Catalytic Science SeriesGold Catalysis, pp. 445-500 (2014) No AccessCHAPTER 12: RECENT DEVELOPMENTS IN ASYMMETRIC CATALYSISPatrick Y. Toullec, Alexandre Pradal, and Véronique MicheletPatrick Y. ToullecInstitut de Recherche de Chimie Paris, UMR CNRS 8247 — Chimie ParisTech, 11 rue P. et M. Curie, 75231 Paris Cedex 05, France, Alexandre PradalInstitut de Recherche de Chimie Paris, UMR CNRS 8247 — Chimie ParisTech, 11 rue P. et M. Curie, 75231 Paris Cedex 05, France, and Véronique MicheletInstitut de Recherche de Chimie Paris, UMR CNRS 8247 — Chimie ParisTech, 11 rue P. et M. Curie, 75231 Paris Cedex 05, Francehttps://doi.org/10.1142/9781848168534_0012Cited by:4 PreviousNext AboutSectionsPDF/EPUB ToolsAdd to favoritesDownload CitationsTrack CitationsRecommend to Library ShareShare onFacebookTwitterLinked InRedditEmail Abstract: The field of gold catalysis has experienced exponential expansion within the last 15 years [1]. The majority of gold-catalyzed reactions rely on the activation of carbon–carbon π-bonds enhancing the electrophilicity of the unsaturated moiety and therefore favoring nucleophilic additions to the carbon–carbon bond. Rare examples employing the activation of a nucleophilic derivative have been reported. The enantioselective transformations employing gold catalysts have appeared only recently and rely mainly on gold(I) linear chiral complexes, which make the control of stereogenic centers much more difficult [2]. This situation therefore slowed the expansion of the field and made it difficult to generalize chiral systems. This chapter intends to present the seminal examples related to asymmetric catalysis focusing exclusively on the use of a chiral catalyst [3]… FiguresReferencesRelatedDetailsCited By 4Gold‐Catalyzed [3+2]‐Annulations of α‐Aryl Diazoketones with the Tetrasubstituted Alkenes of Cyclopentadienes: High Stereoselectivity and EnantioselectivityChing‐Nung Chen, Wei‐Min Cheng, Jian‐Kai Wang, Tzu‐Hsuan Chao and Mu‐Jeng Cheng et al.15 January 2021 | Angewandte Chemie, Vol. 133, No. 9Gold‐Catalyzed [3+2]‐Annulations of α‐Aryl Diazoketones with the Tetrasubstituted Alkenes of Cyclopentadienes: High Stereoselectivity and EnantioselectivityChing‐Nung Chen, Wei‐Min Cheng, Jian‐Kai Wang, Tzu‐Hsuan Chao and Mu‐Jeng Cheng et al.15 January 2021 | Angewandte Chemie International Edition, Vol. 60, No. 9Gold(I)‐Catalyzed Highly Diastereo‐ and Enantioselective Cyclization–[4+3] Annulation Cascades between 2‐(1‐Alkynyl)‐2‐alken‐1‐ones and AnthranilsRahul Dadabhau Kardile, Tzu‐Hsuan Chao, Mu‐Jeng Cheng and Rai‐Shung Liu15 April 2020 | Angewandte Chemie, Vol. 132, No. 26Gold(I)‐Catalyzed Highly Diastereo‐ and Enantioselective Cyclization–[4+3] Annulation Cascades between 2‐(1‐Alkynyl)‐2‐alken‐1‐ones and AnthranilsRahul Dadabhau Kardile, Tzu‐Hsuan Chao, Mu‐Jeng Cheng and Rai‐Shung Liu15 April 2020 | Angewandte Chemie International Edition, Vol. 59, No. 26 Gold CatalysisMetrics History PDF download