Influence of (RGO)/(ferrite) ratios and graphene reduction degree on microwave absorption properties of graphene composites
2015; Elsevier BV; Volume: 644; Linguagem: Inglês
10.1016/j.jallcom.2015.05.073
ISSN1873-4669
AutoresZong Meng, Ying Huang, Na Zhang, Haiwei Wu,
Tópico(s)Graphene research and applications
ResumoThe reduced graphene oxide (RGO)/cobalt ferrite (CoFe2O4) composites with three different (RGO)/(CoFe2O4) ratios were synthesized by a one-pot hydrothermal route. To research the influence of graphene reduction degree on electromagnetic parameters of graphene composites, RGO/CoFe2O4-2 was treated further by reduction process with different reducing agents (N2H4/NaBH4). The crystalline structure, morphology, thermal stability, magnetic property of the synthesized samples were characterized by XRD, TEM, SEM, FT-IR, Raman, TG, VSM and XPS. The absorption properties of the RGO/CoFe2O4 composites were studied. The maximum RL of RGO/CoFe2O4-2 composite is −47.9 dB at 12.4 GHz with a thickness of 2.3 mm, and the absorption bandwidth with the RL below −10 dB is up to 5.0 GHz (from 12.4 to 17.4 GHz) with a thickness of 2.0 mm. The results indicated that the RGO/CoFe2O4 composites have remarkably electromagnetic performance, which are attributed to effective complementarities between the dielectric loss and the magnetic loss. Additionally, the microwave absorption properties of the RGO/CoFe2O4 composites can be tuned easily by varying the (RGO)/(CoFe2O4) ratio, the reduction degree of graphene and layer thickness of the samples.
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