Artigo Acesso aberto Revisado por pares

Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

2017; Royal Society of Chemistry; Volume: 8; Issue: 4 Linguagem: Inglês

10.1039/c6sc05581h

ISSN

2041-6539

Autores

Patrick Williamson, Alicia Galván, Matthew J. Gaunt,

Tópico(s)

Synthesis and Catalytic Reactions

Resumo

A cobalt-catalysed C-H carbonylation of aliphatic carboxamide derivatives is described, employing commercially available Co(ii)-salts in the presence of a silver oxidant. This operationally simple process utilises an atmospheric pressure of CO and generates a range of substituted succinimide products bearing diverse functional groups that can be successfully accessed

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