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Discovery of high-performance low-cost n-type Mg3Sb2-based thermoelectric materials with multi-valley conduction bands

2017; Nature Portfolio; Volume: 8; Issue: 1 Linguagem: Inglês

10.1038/ncomms13901

2041-1723

Jiawei Zhang, Lirong Song, Steffen Hindborg Pedersen, H. Yin, Le Thanh Hung, Bo B. Iversen,

Thermal Expansion and Ionic Conductivity

Abstract Widespread application of thermoelectric devices for waste heat recovery requires low-cost high-performance materials. The currently available n-type thermoelectric materials are limited either by their low efficiencies or by being based on expensive, scarce or toxic elements. Here we report a low-cost n-type material, Te-doped Mg 3 Sb 1.5 Bi 0.5 , that exhibits a very high figure of merit zT ranging from 0.56 to 1.65 at 300−725 K. Using combined theoretical prediction and experimental validation, we show that the high thermoelectric performance originates from the significantly enhanced power factor because of the multi-valley band behaviour dominated by a unique near-edge conduction band with a sixfold valley degeneracy. This makes Te-doped Mg 3 Sb 1.5 Bi 0.5 a promising candidate for the low- and intermediate-temperature thermoelectric applications.