Electronic structures and photophysics of d8-d8 complexes
2017; Elsevier BV; Volume: 345; Linguagem: Inglês
10.1016/j.ccr.2017.01.008
ISSN1873-3840
AutoresHarry B. Gray, Stanislav Záliš, Antonı́n Vlček,
Tópico(s)Lanthanide and Transition Metal Complexes
ResumoResearch on d8-d8 complexes is being actively pursued, owing, in part, to newly developed time-resolved optical, IR, and X-ray methods that directly interrogate bonding changes upon excitation. Our review covers work on the ground- and electronic excited states, as well as the oxidized and reduced forms, of these complexes. Recent experimental and theoretical results add a new chapter to the rich history of d8-d8 spectroscopic and chemical behavior.
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