Artigo Revisado por pares

Heat capacity of VO2 single crystals

1973; Elsevier BV; Volume: 8; Issue: 4 Linguagem: Inglês

10.1016/0025-5408(73)90039-1

ISSN

1873-4227

Autores

G. V. Chandrashekhar, H. L. C. Barros, J.M. Honig,

Tópico(s)

Gas Sensing Nanomaterials and Sensors

Resumo

The heat capacity of VO2 was remeasured both above and below the transition temperature range of 330 – 345 K. For 150 < T < 320 K the results could be fit to the standard Debye theory with a Debye temperature θD = 750 K; for 360 < T < 720 K no Debye temperature could be assigned to the data, which exceeded the equipartition value for Cv above 580 K. The enthalpy of transition was found to be 1.12 k cal/mole VO2.

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