Iron(III) Chloride‐Mediated Regio‐ and Stereoselective Chlorosulfonylation of Alkynes and Alkenes with Sodium Sulfinates
2017; Wiley; Volume: 359; Issue: 5 Linguagem: Inglês
10.1002/adsc.201601211
ISSN1615-4169
AutoresKui Zeng, Lang Chen, Yi Chen, Yongping Liu, Yongbo Zhou, Chak‐Tong Au, Shuang‐Feng Yin,
Tópico(s)Synthesis and Catalytic Reactions
ResumoAbstract The atom‐economic and one‐pot regio‐ and stereoselective addition of sodium arenesulfinates to either alkynes or alkenes can be achieved with an iron(III) chloride hexahydrate [FeCl 3 ⋅6 H 2 O] catalytic system to afford β‐haloalkenyl and β‐chloroalkyl sulfones in moderate to good yields. magnified image
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