Tuning the stacking behaviour of a 2D covalent organic framework through non-covalent interactions
2017; Royal Society of Chemistry; Volume: 1; Issue: 7 Linguagem: Inglês
10.1039/c6qm00378h
ISSN2052-1537
AutoresFrederik Haase, Kerstin Gottschling, Linus Stegbauer, Luzia S. Germann, Rico Gutzler, Viola Düppel, Vijay S. Vyas, Klaus Kern, Robert E. Dinnebier, Bettina V. Lotsch,
Tópico(s)Luminescence and Fluorescent Materials
ResumoThe distinct stacking behaviour of two related 2D covalent organic frameworks is traced back to geometric and electronic features of their building blocks. Self-complementarity and donor–acceptor-type interactions are identified as design principles to access highly crystalline COFs.
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