Artigo Acesso aberto Revisado por pares

Tuning the stacking behaviour of a 2D covalent organic framework through non-covalent interactions

2017; Royal Society of Chemistry; Volume: 1; Issue: 7 Linguagem: Inglês

10.1039/c6qm00378h

ISSN

2052-1537

Autores

Frederik Haase, Kerstin Gottschling, Linus Stegbauer, Luzia S. Germann, Rico Gutzler, Viola Düppel, Vijay S. Vyas, Klaus Kern, Robert E. Dinnebier, Bettina V. Lotsch,

Tópico(s)

Luminescence and Fluorescent Materials

Resumo

The distinct stacking behaviour of two related 2D covalent organic frameworks is traced back to geometric and electronic features of their building blocks. Self-complementarity and donor–acceptor-type interactions are identified as design principles to access highly crystalline COFs.

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