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Post-Synthetic Modification of Mesoporous Zinc-Adeninate Framework with Tris(2,2′-bipyridine) Ruthenium(II) Complex and its Electrochemiluminescence

2017; Wiley; Volume: 38; Issue: 4 Linguagem: Inglês

10.1002/bkcs.11115

1229-5949

Ji Eun Park, Hyojae Oh, Jihyun An, Ik‐Soo Shin,

Covalent Organic Framework Applications

Herein we report a redox-active metal-organic framework (MOF) via post-synthetic cation exchange with tris(2,2′-biprydine) ruthenium(II) complex (Ru(bpy)32+). A porous anionic zinc-adeninate framework (bMOF-100) is spacious enough to easily entrap 2.43 of Ru(bpy)32+ cations within the mesopore. The encapsulation supported the framework structure preventing any distortion from a rapid solvent evaporation under SEM observation. Ru(bpy)32+@bMOF-100 was then immobilized on the surface of glassy carbon electrode, and its electrocatalytic and electrochemiluminescent (ECL) properties were investigated in aqueous and organic solution. Especially, Ru(bpy)32+@bMOF-100 showed the excellent electrochemical properties of Ru(bpy)32+, but gradual decomposition of the MOF structure was observed under electrochemical measurements because of the sluggish oxidation of adeninate ligand.