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Robust Binding between Carbon Nitride Nanosheets and a Binuclear Ruthenium(II) Complex Enabling Durable, Selective CO 2 Reduction under Visible Light in Aqueous Solution

2017; Wiley; Volume: 56; Issue: 17 Linguagem: Inglês

10.1002/anie.201701627

1521-3773

Ryo Kuriki, Muneaki Yamamoto, Kimitaka Higuchi, Yuta Yamamoto, Masato Akatsuka, Daling Lu, Shinya Yagi, Tomoko Yoshida, Osamu Ishitani, Kazuhiko Maeda,

Catalytic Processes in Materials Science

Carbon nitride nanosheets (NS-C3 N4 ) were found to undergo robust binding with a binuclear ruthenium(II) complex (RuRu') even in basic aqueous solution. A hybrid material consisting of NS-C3 N4 (further modified with nanoparticulate Ag) and RuRu' promoted the photocatalytic reduction of CO2 to formate in aqueous media, in conjunction with high selectivity (approximately 98 %) and a good turnover number (>2000 with respect to the loaded Ru complex). These represent the highest values yet reported for a powder-based photocatalytic system during CO2 reduction under visible light in an aqueous environment. We also assessed the desorption of RuRu' from the Ag/C3 N4 surface, a factor that can contribute to a loss of activity. It was determined that desorption is not induced by salt additives, pH changes, or photoirradiation, which partly explains the high photocatalytic performance of this material.