Synthesis, Characterization, and Photocatalytic Properties of Bismuth (III)-benzene-1,3,5-tricarboxylate
2017; Wiley; Volume: 643; Issue: 10 Linguagem: Inglês
10.1002/zaac.201700096
ISSN1521-3749
AutoresFan Ye, Zhi‐Xian Wei, Jiang‐Feng Song, Xu-Hong Wu, Pan Yue,
Tópico(s)Covalent Organic Framework Applications
ResumoZeitschrift für anorganische und allgemeine ChemieVolume 643, Issue 10 p. 669-674 Article Synthesis, Characterization, and Photocatalytic Properties of Bismuth (III)-benzene-1,3,5-tricarboxylate Fan Ye, Fan Ye Department of Chemistry, School of Science, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. ChinaSearch for more papers by this authorZhi-Xian Wei, Corresponding Author Zhi-Xian Wei zx_wei@126.com Department of Safety Science and Engineering, Chemical Engineering and Environment Institute, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. China Prof. Dr. Z.-X. Wei E-Mail: zx_wei@126.com Prof. Dr. J.-F. Song E-Mail: jfsong0129@nuc.edu.cnSearch for more papers by this authorJiang-Feng Song, Corresponding Author Jiang-Feng Song jfsong0129@nuc.edu.cn Department of Chemistry, School of Science, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. China Prof. Dr. Z.-X. Wei E-Mail: zx_wei@126.com Prof. Dr. J.-F. Song E-Mail: jfsong0129@nuc.edu.cnSearch for more papers by this authorXu-Hong Wu, Xu-Hong Wu Department of Chemistry, School of Science, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. ChinaSearch for more papers by this authorPan Yue, Pan Yue Department of Safety Science and Engineering, Chemical Engineering and Environment Institute, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. ChinaSearch for more papers by this author Fan Ye, Fan Ye Department of Chemistry, School of Science, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. ChinaSearch for more papers by this authorZhi-Xian Wei, Corresponding Author Zhi-Xian Wei zx_wei@126.com Department of Safety Science and Engineering, Chemical Engineering and Environment Institute, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. China Prof. Dr. Z.-X. Wei E-Mail: zx_wei@126.com Prof. Dr. J.-F. Song E-Mail: jfsong0129@nuc.edu.cnSearch for more papers by this authorJiang-Feng Song, Corresponding Author Jiang-Feng Song jfsong0129@nuc.edu.cn Department of Chemistry, School of Science, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. China Prof. Dr. Z.-X. Wei E-Mail: zx_wei@126.com Prof. Dr. J.-F. Song E-Mail: jfsong0129@nuc.edu.cnSearch for more papers by this authorXu-Hong Wu, Xu-Hong Wu Department of Chemistry, School of Science, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. ChinaSearch for more papers by this authorPan Yue, Pan Yue Department of Safety Science and Engineering, Chemical Engineering and Environment Institute, 3 Xueyuan Road, 030051 Taiyuan, Shanxi, P. R. ChinaSearch for more papers by this author First published: 12 April 2017 https://doi.org/10.1002/zaac.201700096Citations: 12Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract {[Bi(BTC)(H2O)2]·H2O}n (H3BTC = 1,3,5-benzenetricarboxylic acid) was synthesized by an eco-friendly hydrothermal method and characterized by single-crystal X-ray diffraction, IR and UV/Vis spectroscopy, photoluminescence (PL), and thermogravimetric analyses. The complex featured a 3D metal-organic framework with Bi2 secondary building units. In the complex, the central Bi3+ is nine-coordinate, three central Bi atoms and three BTC3– anions are interconnected into a ring with the dimension of 7.95 × 9.89 Å2. Moreover, the complex is decomposed at over 388 °C, showing its highly thermal stability. Further, the complex exhibits photocatalytic activity for the degradation of methyl orange (MO) solution under UV light irradiation, and its structure can keep consistent with the original one after 9 h photocatalytic reaction, indicating that it is also very stable under UV light. Therefore, it could be anticipated the novel coordination complex will be a stable ultraviolet light catalyst. Citing Literature Supporting Information Supporting information for this article is available on the WWW under https://doi.org/10.1002/zaac.201700096 or from the author. Filename Description zaac201700096-sup-0001-SupMat.pdf774.4 KB Supporting Information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume643, Issue10May 18, 2017Pages 669-674 RelatedInformation
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