Portal de Periódicos da CAPES

Cp 2 TiCl: An Ideal Reagent for Green Chemistry?

2017; American Chemical Society; Volume: 21; Issue: 7 Linguagem: Inglês

10.1021/acs.oprd.7b00098

1520-586X

María Castro Rodríguez, Ignacio Rodríguez‐García, Roman Rodriguez‐Maecker, Laura Pozo Morales, J. Enrique Oltra, Antonio Rosales,

Chemistry and Chemical Engineering

The development of Green Chemistry inevitably involves the development of green reagents. In this review, we highlight that Cp2TiCl is a reagent widely used in radical and organometallic chemistry, which shows, if not all, at least some of the 12 principles summarized for Green Chemistry, such as waste minimization, catalysis, safer solvents, toxicity, energy efficiency, and atom economy. Also, this complex has proved to be an ideal reagent for green C–C and C–O bond forming reactions, green reduction, isomerization, and deoxygenation reactions of several functional organic groups as we demonstrate throughout the review.