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Direct β-Selective Hydrocarboxylation of Styrenes with CO 2 Enabled by Continuous Flow Photoredox Catalysis

2017; American Chemical Society; Volume: 139; Issue: 40 Linguagem: Inglês

10.1021/jacs.7b05942

1943-2984

Hyowon Seo, Aofei Liu, Timothy F. Jamison,

Radical Photochemical Reactions

The direct β-selective hydrocarboxylation of styrenes under atmospheric pressure of CO2 has been developed using photoredox catalysis in continuous flow. The scope of this methodology was demonstrated with a range of functionalized terminal styrenes, as well as α-substituted and β-substituted styrenes.