PEO/garnet composite electrolytes for solid-state lithium batteries: From “ceramic-in-polymer” to “polymer-in-ceramic”
2017; Elsevier BV; Volume: 46; Linguagem: Inglês
10.1016/j.nanoen.2017.12.037
ISSN2211-3282
AutoresLong Chen, Yutao Li, Shuai-Peng Li, Li‐Zhen Fan, Ce‐Wen Nan, John B. Goodenough,
Tópico(s)Advanced Battery Technologies Research
ResumoComposite polyethylene-oxide/garnet electrolytes containing LiTFSI as the lithium salt have a Li+ conductivity σLi > 10−4 S cm−1 at 55 °C and a low plating/stripping impedance of a dendrite-free Li-metal anode; they have been developed for a safe solid-state Li-metal rechargeable battery. Composites consisting of "ceramic-in-polymer" to "polymer-in-ceramic" that are flexible and mechanically robust are fabricated by hot-pressing. Safe pouch cells with a remarkable flexibility have been fabricated. Solid-state LiFePO4|Li batteries with electrolytes of "ceramic-in-polymer" and "polymer-in-ceramic" deliver excellent cycling stability with high discharge capacities (139.1 mAh g–1 with capacity retention of 93.6% after 100 cycles) and high capacity retention (103.6% with coulombic efficiency of 100% after 50 cycles) at 0.2 C and 55 °C. Both kinds of electrolytes can be applied to solid-state lithium batteries.
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