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Polarized Potential Window Available at the Interface Between an Aqueous Electrolyte Solution and Tetraalkylammonium Imide Salts

2004; The Electrochemical Society of Japan; Volume: 72; Issue: 12 Linguagem: Inglês

10.5796/electrochemistry.72.833

2186-2451

Takashi Kakiuchi, Norihiro Tsujioka, Kenji Sueishi, Naoya Nishi, Masahiro Yamamoto,

Analytical Chemistry and Sensors

The polarized potential window (ppw) of 450 mV is available at the interface between water (W) and the room-temperature molten salt (RTMS) that consists of tetraoctylammonium cations and trifluoromethylsulfonylnonafluoro-butylsulfonylimide anions. The ppw at the interface between W and RTMS made of several combinations of hydrophobic cations and anions is correlated with the standard ion-transfer potentials of the ions at the 1,2-dichloroethane | W interface. This correlation is useful not only to predict the width of the ppw but also to approximately estimate the point of zero charge at the RTMS | W interface.