Fabrication of a Co(OH) 2 /ZnCr LDH “p–n” Heterojunction Photocatalyst with Enhanced Separation of Charge Carriers for Efficient Visible-Light-Driven H 2 and O 2 Evolution
2018; American Chemical Society; Volume: 57; Issue: 7 Linguagem: Inglês
10.1021/acs.inorgchem.7b03213
ISSN1520-510X
AutoresDipti Prava Sahoo, Susanginee Nayak, K. Hemalata Reddy, Satyabadi Martha, Kulamani Parida,
Tópico(s)Copper-based nanomaterials and applications
ResumoPhotocatalytic generation of H2 and O2 by water splitting remains a great challenge for clean and sustainable energy. Taking into the consideration promising heterojunction photocatalysts, analogous energy issues have been mitigated to a meaningful extent. Herein, we have architectured a highly efficient bifunctional heterojunction material, i.e., p-type Co(OH)2 platelets with an n-type ZnCr layered double hydroxide (LDH) by an ultrasonication method. Primarily, the Mott–Schottky measurements confirmed the n- and p-type semiconductive properties of LDH and CH material, respectively, with the construction of a p–n heterojunction. The high resolution transmission electron microscopy results suggest that surface modification of ZnCr LDH by Co(OH)2 hexagonal platelets could form a fabulous p–n interfacial region that significantly decreases the energy barrier for O2 and H2 production by effectively separating and transporting photoinduced charge carriers, leading to enhanced photoreactivity. A deep investigation into the mechanism shows that a 30 wt % Co(OH)2-modified ZnCr LDH sample liberates maximum H2 and O2 production in 2 h, i.e., 1115 and 560 μmol, with apparent conversion efficiencies of H2 and O2 evolution of 13.12% and 6.25%, respectively. Remarkable photocatalytic activity with energetic charge pair transfer capability was illustrated by electrochemical impedance spectroscopy, linear sweep voltammetry, and photoluminescence spectra. The present study clearly suggests that low-cost Co(OH)2 platelets are the most crucial semiconductors to provide a new p–n heterojunction photocatalyst for photocatalytic H2 and O2 production on the platform of ZnCr LDH.
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