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Chemoselective deoxygenation of ether-substituted alcohols and carbonyl compounds by B(C 6 F 5 ) 3 -catalyzed reduction with (HMe 2 SiCH 2 ) 2

2018; Royal Society of Chemistry; Volume: 54; Issue: 38 Linguagem: Inglês

10.1039/c8cc01163j

1364-548X

Wenyu Yang, Lu Gao, Ji Lu, Zhenlei Song,

Catalytic Cross-Coupling Reactions

B(C 6 F 5 ) 3 -catalyzed deoxygenation of ether-substituted alcohols and carbonyl compounds has been developed using (HMe 2 SiCH 2 ) 2 as the reductant. This reagent shows distinct superiority over traditional one silicon-centered hydrosilanes, giving the corresponding alkanes in high yields with good tolerance of ethers, aryl halides and alkenes.