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Stack performances in high temperature steam electrolysis and co-electrolysis

2015; Elsevier BV; Volume: 40; Issue: 35 Linguagem: Inglês

10.1016/j.ijhydene.2015.04.085

1879-3487

M. Reytier, Stéphane Di Iorio, André Chatroux, Marie Petitjean, Julie Cren, Myriam de Saint Jean, J. Aicart, Julie Mougin,

Catalysis and Oxidation Reactions

High Temperature Steam Electrolysis (HTSE), based on solid oxide electrolysis cells (SOE) is a promising way to produce massively hydrogen with high efficiencies. This technology also allows producing syngas (H2 + CO) by co-electrolyzing a mix of steam and CO2. This syngas constitutes the basis to obtain further synthetic fuels. For both HTSE and co-electrolysis, durability and cost are still key points, but additionally for co-electrolysis the outlet H2/CO gas composition has to be tailored to fit with the targeted fuels. Previous works have been carried out to develop a stack design suitable for both applications. Here experiments at stack level in both electrolysis and co-electrolysis modes have been carried out. A 10-cell stack and a 25-cell stack have been tested in electrolysis mode, respectively producing 0.6 Nm3/h and 1.7 Nm3/h of hydrogen at 800 °C below the thermoneutral voltage (1.3 V) for all the cells and a steam conversion around 50%, with a small scattering between the different cells. Gas tightness of the stacks has also been evaluated. Moreover, the operation in co-electrolysis has been validated. Finally a cost analysis of this stack design has been performed and shows all the economical potentialities of this technology.