The “Wanderlust” of Me 3 Si groups in rare-earth triple-decker complexes: a combined experimental and computational study
2018; Royal Society of Chemistry; Volume: 54; Issue: 73 Linguagem: Inglês
10.1039/c8cc05317k
ISSN1364-548X
AutoresVolker Lorenz, Phil Liebing, Adrien Bathelier, Felix Engelhardt, Laurent Maron, Liane Hilfert, Sabine Busse, Frank T. Edelmann,
Tópico(s)Synthesis and characterization of novel inorganic/organometallic compounds
ResumoThe migration of Me 3 Si groups (“Wanderlust”) in rare-earth triple-decker sandwich complexes of the type Ln 2 (COT′′) 3 (COT′′ = bis(trimethylsilyl)cyclooctatetraenyl) has been elucidated by a combined experimental and computational study.
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