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BIBTEX RIS

Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I)

2018; American Chemical Society; Volume: 20; Issue: 18 Linguagem: Inglês

10.1021/acs.orglett.8b01989

ISSN

1523-7060

Autores

Quillon J. Simpson, Matthew J. G. Sinclair, David W. Lupton, Adrian B. Chaplin, Joel F. Hooper,

Tópico(s)

Sulfur-Based Synthesis Techniques

Resumo

The use of an isolatable, monomeric Pd(I) complex as a catalyst for the oxidative cross-coupling of aryl-antimony and aryl-boron nucleophiles is reported. This reaction tolerates a wide variety of substrates, with >20:1 selectivity for cross-coupled products. This strategy offers a new approach to achieving the selective cross-coupling of nucleophiles.

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