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Signatures of moiré-trapped valley excitons in MoSe2/WSe2 heterobilayers

2019; Nature Portfolio; Volume: 567; Issue: 7746 Linguagem: Inglês

10.1038/s41586-019-0957-1

1476-4687

Kyle L. Seyler, Pasqual Rivera, Hongyi Yu, Nathan P. Wilson, Essance Ray, David Mandrus, Jiaqiang Yan, Wang Yao, Xiaodong Xu,

Semiconductor Quantum Structures and Devices

The creation of moir\'e patterns in crystalline solids is a powerful approach to manipulate their electronic properties, which are fundamentally influenced by periodic potential landscapes. In 2D materials, a moir\'e pattern with a superlattice potential can form by vertically stacking two layered materials with a twist and/or finite lattice constant difference. This unique approach has led to emergent electronic phenomena, including the fractal quantum Hall effect, tunable Mott insulators, and unconventional superconductivity. Furthermore, theory predicts intriguing effects on optical excitations by a moir\'e potential in 2D valley semiconductors, but these signatures have yet to be experimentally detected. Here, we report experimental evidence of interlayer valley excitons trapped in a moir\'e potential in MoSe$_2$/WSe$_2$ heterobilayers. At low temperatures, we observe photoluminescence near the free interlayer exciton energy but with over 100 times narrower linewidths. The emitter g-factors are homogeneous across the same sample and only take two values, -15.9 and 6.7, in samples with twisting angles near 60{\deg} and 0\deg, respectively. The g-factors match those of the free interlayer exciton, which is determined by one of two possible valley pairing configurations. At a twist angle near 20\deg, the emitters become two orders of magnitude dimmer, but remarkably, they possess the same g-factor as the heterobilayer near 60\deg. This is consistent with the Umklapp recombination of interlayer excitons near the commensurate 21.8{\deg} twist angle. The emitters exhibit strong circular polarization, which implies the preservation of three-fold rotation symmetry by the trapping potential. Together with the power and excitation energy dependence, all evidence points to their origin as interlayer excitons trapped in a smooth moir\'e potential with inherited valley-contrasting physics.