Visible Light Enables Aerobic Iodine Catalyzed Glycosylation
2019; Wiley; Volume: 2019; Issue: 28 Linguagem: Inglês
10.1002/ejoc.201900143
ISSN1434-193X
AutoresMatthias Krumb, Tobias Lucas, Till Opatz,
Tópico(s)Radical Photochemical Reactions
ResumoA versatile protocol for light induced catalytic activation of thioglycosides using iodine as an inexpensive and readily available photocatalyst was developed. Oxygen serves as a green and cost‐efficient terminal oxidant and irradiation is performed with a common household LED‐bulb. The scope of this glycosylation protocol was investigated in the synthesis of O ‐glycosides with yields up to 95 %.
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