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[Zr 6 O 4 (OH) 4 (benzene-1,4-dicarboxylato) 6 ] n : a hexagonal polymorph of UiO-66

2019; Royal Society of Chemistry; Volume: 55; Issue: 42 Linguagem: Inglês

10.1039/c9cc00802k

1364-548X

Maite Perfecto-Irigaray, Garikoitz Beobide, Óscar Castillo, Iván da Silva, Daniel García‐Lojo, Antonio Luque, Ander Mendia, Sonia Pérez‐Yáñez,

Polyoxometalates: Synthesis and Applications

Since its discovery in 2008, the paradigmatic UiO-66 has behaved as the germ that has prompted the chemistry of group-4 metal based metal-organic frameworks, all of them featuring outstanding thermal and chemical stability. Herein we present the first polymorph of UiO-66 and the key conditions that led to its formation.