Oxygen‐Deficient NiFe 2 O 4 Spinel Nanoparticles as an Enhanced Electrocatalyst for the Oxygen Evolution Reaction
2019; Wiley; Volume: 5; Issue: 10 Linguagem: Inglês
10.1002/cnma.201900231
ISSN2199-692X
AutoresDongwook Lim, Hyungseok Kong, Nam-Il Kim, Chaewon Lim, Wha‐Seung Ahn, Sung‐Hyeon Baeck,
Tópico(s)Advanced battery technologies research
ResumoAbstract Herein, mesoporous NiFe 2 O 4 spinel nanoparticles with abundant oxygen vacancies are successfully prepared by a simple hydrothermal method followed by mild H 2 reduction and used as catalysts for the oxygen evolution reaction. Compared with the pristine and air‐treated NiFe 2 O 4 , the H 2 ‐treated NiFe 2 O 4 shows a much lower overpotential of 389 mV at a current density of 10 mA cm −2 . The H 2 ‐treated NiFe 2 O 4 also indicates substantial long‐term stability even after 1000 cyclic tests. This outstanding electrochemical activity and stability can be attributed to the improved physicochemical properties by H 2 treatment: small nanoparticles with well‐developed mesoporous structures, a high ratio of Ni 2+ /Ni 3+ cations, and abundant oxygen vacancies. These properties can significantly improve charge transfer kinetics and increase the number of active sites on the catalyst. The results demonstrate that this facile fabrication method is a promising route for developing cost‐effective and high‐performance catalysts to be used in electrochemical applications.
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