Formation of zirconocene η2-imine complexes by rearrangement of cyclic iminoacyl complexes.
1992; Elsevier BV; Volume: 33; Issue: 38 Linguagem: Inglês
10.1016/s0040-4039(00)61172-3
ISSN1873-3581
AutoresJeremy Davis, Richard J. Whitby, Albert Jaxa‐Chamiec,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoInsertion of phenylisocyanide into bicyclic zirconacyclopentanes, obtained from a 1,7-octa- or 1,6-hepta-diene by reaction with dibutylzirconocene, affords initially an iminoacyl complex that rearranges on warming to form a zirconocene η2-imine complex which inserts unactivated alkenes and alkynes.
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