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Selective Monoalkylation of Ammonia: A High Throughput Synthesis of Primary Amines

1999; Thieme Medical Publishers (Germany); Volume: 1999; Issue: 11 Linguagem: Inglês

10.1055/s-1999-2946

1437-2096

Sukanta Bhattacharyya, Kurt A. Neidigh, Mitchell A. Avery, J. Williamson,

Ammonia Synthesis and Nitrogen Reduction

Primary amines are obtained in good to excellent yields by highly selective monoalkylation of ammonia with alkyl and aryl ketones using titanium(IV) isopropoxide and sodium borohydride.