Portal de Periódicos da CAPES

Palladium (O) catalyzed tandem alkylation and SN′ cyclization of 1,4-dichlorobut-2-ene by the N-(diphenylmethylene)acetonitrile. A stereoselective synthesis of 1-aminocyclopropanecarboxylic acids

1995; Elsevier BV; Volume: 36; Issue: 17 Linguagem: Inglês

10.1016/0040-4039(95)00381-l

1873-3581

A Gaucher, Philippe Dorizon, Jean Ollivier, Jacques Salaün,

Asymmetric Synthesis and Catalysis

Racemic coronamic acid has been prepared with 100% diastereoselectivity from one pot palladium (O) catalyzed alkylation and SN′ cyclization of 1,4-dichlorobut-2-ene by the benzophenone Schiff base of aminoacetonitrile.