Synthetic studies of viridenomycin. Construction of the cyclopentene carboxylic acid part
2000; Elsevier BV; Volume: 41; Issue: 11 Linguagem: Inglês
10.1016/s0040-4039(00)00013-7
ISSN1873-3581
AutoresJun Ishihara, Koji Hagihara, Hiroyuki Chiba, Kouichi Ito, Yumiko Yanagisawa, Kiichiro Totani, Kin‐ichi Tadano,
Tópico(s)Marine Sponges and Natural Products
ResumoA highly functionalized cyclopentene carboxylic acid derivative, as an advanced synthetic intermediate of viridenomycin, was synthesized. The synthesis commenced with the previously reported highly functionalized tetrahydrofuran derivative prepared from d-glucose. The stereochemical confirmation of the present final compound was conducted by comparison with a compound synthesized very recently by the Meyers group.
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