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The Formation of ReS 2 Inorganic Fullerene-like Structures Containing Re 4 Parallelogram Units and Metal−Metal Bonds

2002; American Chemical Society; Volume: 124; Issue: 39 Linguagem: Inglês

10.1021/ja0261630

1943-2984

Karl S. Coleman, Jeremy Sloan, Neal A. Hanson, Gareth Brown, Gerald P. Clancy, Mauricio Terrones, Humberto Terrones, Malcolm L. H. Green,

Inorganic Chemistry and Materials

The encapsulation of ReO(x) within ReS(2) inorganic fullerene-like cages is described for the first time. The encapsulate was prepared by the sulfidization of both hand-milled and ball-milled samples of ReO(2); partial conversion of the oxide to the sulfide was achieved with the degree of sulfidization depending on the exposure to the sulfidizing agent, H(2)S.