Highly Efficient β-Glucosylation of the Acidic Hydroxyl Groups, Phenol and Carboxylic Acid, with an Peracetylated Glucosyl Fluoride Using a Combination of BF 3 · Et 2 O and DTBMP as a Promoter
1999; Thieme Medical Publishers (Germany); Volume: 1999; Issue: 10 Linguagem: Inglês
10.1055/s-1999-12529
ISSN1437-2096
Autores Tópico(s)Chemical Synthesis and Reactions
ResumoA combination of BF3 · Et2O and DTBMP was established to be an efficient promoter of β-glucosylation of both phenols and carboxylic acids with a peracetylated glycosyl fluoride (2). This new method achieved remarkably high yields and β-selectivity.
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