Early transition metal thiolates
1996; Elsevier BV; Volume: 147; Linguagem: Inglês
10.1016/0010-8545(95)01134-x
ISSN1873-3840
AutoresDouglas W. Stephan, T. Timothy Nadasdi,
Tópico(s)Metal complexes synthesis and properties
ResumoThis article presents a comprehensive and systematic review of the syntheses, structures and reactivities of thiolate complexes of group 4 and 5 metals (i.e. Ti, Zr, Hf, V, Nb and Ta). This includes a discussion of monometallic and polymetallic species as well as recent advances in heterobimetallic derivatives. Specifically excluded are dithiolene derivatives of the early metals as these compounds have been previously reviewed.
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