Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes
2004; Elsevier BV; Volume: 46; Issue: 1 Linguagem: Inglês
10.1016/j.tetlet.2004.10.168
ISSN1873-3581
AutoresMakoto Nakajima, Shunsuke Kotani, Tadao Ishizuka, Shunichi Hashimoto,
Tópico(s)Advanced Synthetic Organic Chemistry
ResumoThe effectiveness of chiral phosphine oxide BINAPO as a catalyst for the enantioselective addition of allyltrichlorosilanes to aldehydes was demonstrated, wherein the combination of diisopropylethylamine and tetrabutylammonium iodide as additives is crucial for accelerating the catalytic cycle.
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